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Bulk modulus

 

Numerical constant that describes the elastic properties of a solid or fluid under pressure from all sides. It is the ratio of the tensile strength or compressive force per unit surface area to the change in volume per unit volume of the solid or fluid and thus is a measure of a substance's ability to resist deformation. Its units are newtons per square metre (N/m2). Matter that is difficult to compress has a large bulk modulus; for example, steel has a bulk modulus of 1.6 1011 N/m2, three times that of glass (i.e., glass is three times more compressible than steel).

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Bulk modulus

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Illustration of uniform compression

The bulk modulus (K) of a substance measures the substance's resistance to uniform compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting relative decrease of the volume. Its base unit is the pascal.[1]

Contents

Definition

The bulk modulus K>0 can be formally defined by the equation:

K=-V\frac{\mathrm d P}{\mathrm d V}

where P is pressure, V is volume, and dP/dV denotes the derivative of pressure with respect to volume. Equivalently

K=\rho \frac{\partial P}{\partial \rho}

where ρ is density and dp/dρ denotes the derivative of pressure with respect to density. The inverse of the bulk modulus gives a substance's compressibility.

Other moduli describe the material's response (strain) to other kinds of stress: the shear modulus describes the response to shear, and Young's modulus describes the response to linear stress. For a fluid, only the bulk modulus is meaningful. For an anisotropic solid such as wood or paper, these three moduli do not contain enough information to describe its behaviour, and one must use the full generalized Hooke's law.

Thermodynamic relation

Strictly speaking, the bulk modulus is a thermodynamic quantity, and it is necessary to specify how the temperature varies in order to specify a bulk modulus: constant-temperature (isothermal K_T), constant-entropy (adiabatic K_S), and other variations are possible. In practice, such distinctions are usually only relevant for gases.

For an ideal gas, the adiabatic bulk modulus K_S is given by


K_S=\gamma\, P

and the isothermal bulk modulus K_T is given by


K_T=P\,

where

γ is the adiabatic index, sometimes called κ.
P is the pressure.

When the gas is not ideal, these equations give only an approximation of the bulk modulus. In a fluid, the bulk modulus K and the density ρ determine the speed of sound c (pressure waves), according to the Newton-Laplace formula

c=\sqrt{\frac{K}{\rho}}.

Solids can also sustain transverse waves: for these materials one additional elastic modulus, for example the shear modulus, is needed to determine wave speeds.

Measurement

It is possible to measure the bulk modulus using powder diffraction under applied pressure.

Selected values

Approximate bulk modulus (K) for common materials
Material Bulk modulus in Pa Bulk modulus in ksi
Glass (see also diagram below table) 3.5×1010 to 5.5×1010 5.8×103
Steel 1.6×1011 23×103
Diamond[2] 4.42×1011 64×103
Influences of selected glass component additions on the bulk modulus of a specific base glass.[3]

Material with bulk modulus value of 35GPa needs external pressure of 0.35 GPa (~3500Bar) to reduce the volume by one percent.

Approximate bulk modulus (K) for other substances
Water 2.2×109 Pa (value increases at higher pressures)
Air 1.42×105 Pa (adiabatic bulk modulus)
Air 1.01×105 Pa (constant temperature bulk modulus)
Solid helium 5×107 Pa (approximate)

References

  1. ^ "Bulk Elastic Properties". hyperphysics. Georgia State University. http://hyperphysics.phy-astr.gsu.edu/hbase/permot3.html. 
  2. ^ Cohen, Marvin (1985). "Calculation of bulk moduli of diamond and zinc-blende solids". Phys. Rev. B 32: 7988–7991. Bibcode 1985PhRvB..32.7988C. doi:10.1103/PhysRevB.32.7988. 
  3. ^ Fluegel, Alexander. "Bulk modulus calculation of glasses". glassproperties.com. http://www.glassproperties.com/bulk_modulus/. 
Conversion formulas
Homogeneous isotropic linear elastic materials have their elastic properties uniquely determined by any two moduli among these, thus given any two, any other of the elastic moduli can be calculated according to these formulas.
(K,\,E) (K,\,\lambda) (K,\,G) (K,\, \nu) (E,\,G) (E,\,\nu) (\lambda,\,G) (\lambda,\,\nu) (G,\,\nu) (G,\,M)
K=\, \tfrac{EG}{3(3G-E)} \tfrac{E}{3(1-2\nu)} \lambda+ \tfrac{2G}{3} \tfrac{\lambda(1+\nu)}{3\nu} \tfrac{2G(1+\nu)}{3(1-2\nu)} M - \tfrac{4G}{3}
E=\, \tfrac{9K(K-\lambda)}{3K-\lambda} \tfrac{9KG}{3K+G} 3K(1-2\nu)\, \tfrac{G(3\lambda + 2G)}{\lambda + G} \tfrac{\lambda(1+\nu)(1-2\nu)}{\nu} 2G(1+\nu)\, \tfrac{G(3M-4G)}{M-G}
\lambda=\, \tfrac{3K(3K-E)}{9K-E} K-\tfrac{2G}{3} \tfrac{3K\nu}{1+\nu} \tfrac{G(E-2G)}{3G-E} \tfrac{E\nu}{(1+\nu)(1-2\nu)} \tfrac{2 G \nu}{1-2\nu} M - 2G\,
G=\, \tfrac{3KE}{9K-E} \tfrac{3(K-\lambda)}{2} \tfrac{3K(1-2\nu)}{2(1+\nu)} \tfrac{E}{2(1+\nu)} \tfrac{\lambda(1-2\nu)}{2\nu}
\nu=\, \tfrac{3K-E}{6K} \tfrac{\lambda}{3K-\lambda} \tfrac{3K-2G}{2(3K+G)} \tfrac{E}{2G}-1 \tfrac{\lambda}{2(\lambda + G)} \tfrac{M - 2G}{2M - 2G}
M=\, \tfrac{3K(3K+E)}{9K-E} 3K-2\lambda\, K+\tfrac{4G}{3} \tfrac{3K(1-\nu)}{1+\nu} \tfrac{G(4G-E)}{3G-E} \tfrac{E(1-\nu)}{(1+\nu)(1-2\nu)} \lambda+2G\, \tfrac{\lambda(1-\nu)}{\nu} \tfrac{2G(1-\nu)}{1-2\nu}

 
 

 

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